That’s odd! My guess is he’s stressed and is showing his stress. I saw your other post about the kittens…is HE neutered? Do you have 4 litterboxes (one per cat plus one)? Are those litterboxes VERY clean?
Bringing in new animals cause upheaval in a home, even if you do it the right way with slow introductions. ASSUMING HE IS IN GOOD HEALTH, and assuming you’ve had him checked since this started, I’d suggest picking up some feliway from petsmart or petco. I’d also prevent him from going into the bathroom with you.
Please check your original question here, and please keep all additional, related questions to your original post so we’re not hopping all over the place to connect the dots. 🙂